文献类型：期刊文献

英文题名：Preparation of CexZr1-xO2 (x = 0.75, 0.62) solid solution and its application in Pd-only three-way catalysts

作者：Guo, Yun[1]; Lu, Guanzhong[1]; Zhang, Zhigang[1]; Zhang, Shunhai[1]; Qi, Yan[1]; Liu, Yi[1]

机构：[1] Lab for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai, 200237, China

年份：2007

卷号：126

期号：3-4 SPEC. ISS.

起止页码：296

外文期刊名：Catalysis Today

收录：EI(收录号：20073210758800)

语种：英文

外文关键词：Catalyst activity - Cerium compounds - Coprecipitation - Oxidation - Synthesis (chemical)

摘要：Nanoparticles of CexZr1-xO2 (x = 0.75, 0.62) were prepared by the oxidation-coprecipitation method using H2O2 as an oxidant, and characterized by N2 adsorption, XRD and H2-TPR. CexZr1-xO2 prepared had single fluorite cubic structure, good thermal stability and reduction property. With the increasing of Ce/Zr ratio, the surface area of CexZr1-xO2 increased, but thermal stability of CexZr1-xO2 decreased. The surface area of Ce0.62Zr0.38O2 was 41.2 m2/g after calcination in air at 900 °C for 6 h. TPR results showed the formation of solid solution promoted the reduction of CeO2, and the reduction properties of CexZr1-xO2 were enhanced by the cycle of TPR-reoxidation. The Pd-only three-way catalysts (TWC) were prepared by the impregnation method, in which Ce0.75Zr0.25O2 was used as the active washcoat and Pd loading was 0.7 g/L. In the test of Air/Fuel, the conversion of C3H8 was close to 100% and NO was completely converted at λ 3H8 was induced by the steam reform and dissociation adsorption reaction of C3H8. Pd-only catalyst using Ce0.75Zr0.25O2 as active washcoat showed high light off activity, the reaction temperatures (T50) of 50% conversion of CO, C3H8 and NO were 180, 200 and 205 °C, respectively. However, the conversions of C3H8 and NO showed oscillation with continuously increasing the reaction temperature. The presence of La2O3 in washcoat decreased the light off activity and suppressed the oscillation of C3H8 and NO conversion. After being aged at 900 °C for 4 h, the operation windows of catalysts shifted slightly to rich burn. The presence of La2O3 in active washcoat can enhance the thermal stability of catalyst significantly. ? 2007 Elsevier B.V. All rights reserved.