文献类型：期刊文献

英文题名：Recent Advances in Photocatalysis over Metal-Organic Frameworks-Based Materials

作者：Zhang, Yijun[1];Mao, Fangxin[1];Wang, Lijie[1];Yuan, Haiyang[1];Liu, Peng Fei[1];Yang, Hua Gui[1]

机构：[1]East China Univ Sci & Technol, Shanghai Engn Res Ctr Hierarch Nanomat, Sch Mat Sci & Engn, Key Lab Ultrafine Mat,Minist Educ, 130 Meilong Rd, Shanghai 200237, Peoples R China

年份：2020

卷号：4

期号：5

外文期刊名：SOLAR RRL

收录：;EI(收录号：20195207903102);WOS:【SCI-EXPANDED(收录号:WOS:000503202200001)】；

基金：This work was financially supported by National Natural Science Funds for Distinguished Young Scholar (51725201), International (Regional) Cooperation and Exchange Projects of the National Natural Science Foundation of China (51920105003), Innovation Program of Shanghai Municipal Education Commission (E00014), National Natural Science Foundation of China (21573068, 21902048, 51902105), Shanghai Engineering Research Center of Hierarchical Nanomaterials (18DZ2252400), Shanghai Sailing Program (19YF1411600), National Postdoctoral Program for Innovative Talents (BX20190113), and China Postdoctoral Science Foundation Funded Project (2018M641938).

语种：英文

外文关键词：metal-organic frameworks; modification strategies; photocatalytic applications

摘要：To meet the requirements for sustainable development, photocatalytic applications including water splitting, CO2 reduction, pollutant degradation, and organic conversion reactions have become hot topics for research, due to the predictable advantages of energy storage and transportation. Metal-organic frameworks (MOFs) featured with porosity, crystallinity, and tunable constitution offer enormous potential in photocatalytic applications. Herein, a critical overview of MOFs-based photocatalysts is presented. Following a concise introduction of the structural characteristics of MOFs, the synthesis methods of MOFs-based photocatalysts are summarized. Moreover, subtle modification strategies for MOFs inspired by the development of other inorganic photocatalysts are also discussed on the basis of the photocatalytic mechanisms of light absorption, electron transfer, and surface catalytic reactions. Furthermore, the applications of certain MOFs-based photocatalysts are introduced in detail. In addition, other organic frameworks-based photocatalytic materials, such as covalent organic frameworks and covalent triazine frameworks, are also described to provide a guided insight into the rational design and fabrication of efficient frameworks-based photocatalysts. Finally, a brief conclusion and perspective on the opportunities and challenges for the future development of MOFs-based photocatalysts are proposed.