文献类型：期刊文献

英文题名：Fe-catalyzed hydroxytrifluoromethylation of α-(trifluoromethyl)styrenes with CF3SO2Na: facile access to α,β-bistrifluoromethyl tertiary alcohols

作者：Zheng, Pai[1];Liu, Chuan[1];Zeng, Qianding[1];Zhang, Yi[1];Liu, Ying[1];He, Jingjing[1];Deng, Yupian[1];Cao, Song[1,2]

机构：[1]East China Univ Sci & Technol ECUST, Sch Pharm, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

年份：2022

卷号：20

期号：47

起止页码：9302

外文期刊名：ORGANIC & BIOMOLECULAR CHEMISTRY

收录：;EI(收录号：20224813190301);WOS:【SCI-EXPANDED(收录号:WOS:000886577700001)，CCR-EXPANDED(收录号:WOS:000886577700001)】；

语种：英文

外文关键词：Catalysis - Fluorine compounds - Potassium compounds - Sodium compounds

摘要：A mild and practical Fe-catalyzed hydroxytrifluoromethylation of alpha-(trifluoromethyl)styrenes with CF3SO2Na in the presence of K2S2O8 and air was developed. The reaction proceeded efficiently at room temperature without beta-fluoride elimination and afforded the corresponding alpha,beta-bistrifluoromethyl tertiary alcohols in good to excellent yields.