文献类型：期刊文献

英文题名：Microporous assembly and shape control of a new Zn metal-organic framework: Morphology-dependent catalytic performance

作者：Wang, Jiajia[1];Han, Yuqing[1];Xu, Haitao[1];Xu, Zhen-Liang[1]

机构：[1]ECUST, State Key Lab Chem Engn, Shanghai, Peoples R China

年份：2018

卷号：32

期号：2

外文期刊名：APPLIED ORGANOMETALLIC CHEMISTRY

收录：;EI(收录号：20180504692230);WOS:【SCI-EXPANDED(收录号:WOS:000423670000089)】；

基金：We gratefully acknowledge the financial support from the National Natural Science Foundation of China (no. 21371058) and the Ministry of Education (A200-C-1101). This work was supported in part by East China University of Science and Technology (YA0157117).

语种：英文

外文关键词：catalytic performance; crystal structure; micro-/nanocrystals; microporous metal-organic framework

摘要：A new metal-organic framework (MOF), [Zn(ATA)(bpd)] (1Zn) (ATA: 2-aminoterephthalic acid; bpd: 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene), exhibiting a three-dimensional extended porous structure was successfully assembled in a MeOH-H2O solvent system. Under various controlled conditions, 1Zn was obtained in a variety of morphologies such as microspheres, microblocks, microsheets, microplates and microrods. The catalytic performance of the 1Zn microsized MOF was evaluated, and a possible catalytic mechanism was proposed. The flexibility of this MOF assembly strategy for shape control will certainly enhance new potential applications of micro-/nano-MOFs.