文献类型：期刊文献

中文题名：新型丙烯腈催化剂在40ml流化床上的放大研究

英文题名：Studies on New Type Acryionitrile Catalyst in 40ml Fluidized Bed

作者：吴海霞[1];朱晓岺[1];于甦生[1];顾起鹤[1]

机构：[1]华东化工学院催化所,上海200237

年份：1993

卷号：22

期号：8

起止页码：526

中文期刊名：石油化工

外文期刊名：Petrochemical Technology

收录：CSTPCD;;Scopus;北大核心:【北大核心1992】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：丙烯腈;催化剂;流化床反应器

外文关键词：Acrylonitrile, propylene ammoxidation, fluidized bed

摘要：对自行研制的FS系列新型丙烯腈催化剂在40ml流化床上进行了放大研究。得到了该催化剂应用的最佳工艺条件及其最佳制备条件。结果表明,FS系列催化剂催化活性超过进口工业催化剂水平。对FS催化剂的物性测试表明,FS催化剂的活性相主要是NiMoO_4和α相COMoO_4。
The scale-up of a new type FS system acrylonitrile catalyst prepared by the authors has been studied in a 40 ml fluidized bed. The optimum operating conditions and preparative conditions of FS system catalysts are obtained. The results show that the catalytic activity of FS series catalyst is comparable with that of foreigh commercial catalysts. The results of determination of the characteristics of FS series catalysts indicate that the active phase is mainly NiMoO and α-phase CoMoO_4.