文献类型：期刊文献

中文题名：碳酸二甲酯与醋酸苯酯合成碳酸二苯酯的研究

英文题名：Synthesis of Diphenyl Carbonate from Dimethyl Carbonate and Phenylacetate

作者：沈荣春[1];方云进[1];肖文德[1];朱开宏[1]

机构：[1]华东理工大学联合反应工程研究所,上海200237

年份：2002

卷号：31

期号：11

起止页码：897

中文期刊名：石油化工

外文期刊名：Petrochemical Technology

收录：CSTPCD;;Scopus;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：碳酸二甲酯;醋酸苯酯;合成;碳酸二苯酯;研究;酯交换法;二丁基氧化锡;钛酸丁酯;钛酸乙酯

外文关键词：dimethyl carbonate;phenylacetate;transesterification;diphenyl carbonate;di- n -butyltin oxide;butyl titanate;ethyl titanate

摘要：通过碳酸二甲酯与醋酸苯酯进行酯交换合成碳酸二苯酯的研究,筛选合成碳酸二苯酯的催化剂,考察了催化剂浓度、物料配比、温度诸因素对反应的影响,得出了该反应的最佳工艺条件,并与其它合成路线进行了简单的比较。
A transesterification process for synthesis of diphenyl carbonate from dimethyl carbonate and phenylacetate was studied.Some organic-metal catalysts for the reaction were selected.The effects of catalyst concent ration, ratio of reactants and reaction temperature on the reaction were investigated.Based on this,the optimized conditions for the reaction were obtained.This synthetic route was briefly compared with other routes.