详细信息
法国梧桐枯叶基活性炭的制备及其在超级电容器中的应用 ( EI收录)
Preparation of platanus leaf-based activated carbon and its application to supercapacitors
文献类型:期刊文献
中文题名:法国梧桐枯叶基活性炭的制备及其在超级电容器中的应用
英文题名:Preparation of platanus leaf-based activated carbon and its application to supercapacitors
作者:周王帆[1];陈新[1,2];曹红亮[1];王海燕[1];赵仰之[1];贾晓博[1];王曼[1]
机构:[1]华东理工大学材料科学与工程学院,超细材料制备与应用教育部重点实验室,上海市先进聚合物材料重点实验室,上海200237;[2]中国科学院上海微系统与信息技术研究所信息功能材料国家重点实验室,上海200050
年份:2017
卷号:68
期号:7
起止页码:2918
中文期刊名:化工学报
外文期刊名:CIESC Journal
收录:CSTPCD;;EI(收录号:20174304289497);Scopus;北大核心:【北大核心2014】;CSCD:【CSCD2017_2018】;
基金:上海市重点学科和重点实验室项目(B502,08DZ2230500)~~
语种:中文
中文关键词:生物质;活性炭;电化学;法国梧桐;超级电容器;电极材料
外文关键词:biomass; activated carbon; electrochemistry; platanus; supercapacitor; electrode material
摘要:以生物质法国梧桐枯叶为原料,将炭化的枯叶通过KOH化学活化处理,制备法国梧桐枯叶基活性炭(PLAC)。采用扫描电子显微镜(SEM)、X射线能量色散谱(EDS)、X射线光电子能谱(XPS)、傅里叶变换红外光谱(FTIR)、氮气吸脱附对法国梧桐基枯叶活性炭的形貌、成分、比表面积、孔径分布等进行表征;运用三电极电化学体系,通过循环伏安,恒流充放电,循环稳定性测试,电化学阻抗谱分析法国梧桐枯叶基活性炭的超级电容器电极性能。结果显示,在800℃下碳化,通过KOH活化处理的法国梧桐基活性炭制备的电极,在1 A·g^(-1)电流密度下,比电容达到266 F·g^(-1)。电极在5 A·g^(-1)的电流密度下循环2000次后,比容量仍保留97.0%,展示出良好的电极性能。
Platanus leaf-based activated carbon(PLAC) was synthesized through high temperature carbonization and KOH chemical activation, using dry platanus leaves as raw materials. Scanning electron microscopy(SEM), energy dispersive spectrometry(EDS), X-ray photoelectron spectroscopy(XPS), Fourier transform infrared spectroscopy(FTIR) and nitrogen adsorption-desorption techniques were used to characterize the morphology, composition, specific surface area and pore size distribution of the PLAC. The cyclic voltammetric(CV), galvanostatic charge/discharge(GCD) and electrochemical impedance spectroscopy(EIS) characterizations were performed with a three electrode electrochemical system, to study the supercapacitor electrode performance of the PLAC. The result shows that the PLAC electrode obtained under 800℃ carbonization and KOH chemical activation has specific capacitance of 266 F·g^-1 at 1 A·g^-1, and it can remain 97.0% of the initial capacitance after 2000 cycles at 5 A·g^-1, demonstrating good electrode properties.
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