文献类型：期刊文献

英文题名：Syntheses, confirmation and properties of porphyrin oligomers with alkoxyl linkages

作者：Li, XQ; Shi, YY; Yu, LX; Wang, XQ; Liu, GF

机构：[1]Jilin Univ, Coll Chem, Changchun 130023, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Pharmaceut, Shanghai 200237, Peoples R China

年份：2005

卷号：21

期号：3

起止页码：253

外文期刊名：CHEMICAL RESEARCH IN CHINESE UNIVERSITIES

收录：;EI(收录号：2005279198008);WOS:【SCI-EXPANDED(收录号:WOS:000229624800001)】；

语种：英文

外文关键词：synthesis; characterization; porphyrin oligomers; alkoxyl linkages

摘要：A new and general synthesis of a porphyrinK( I) with two alkoxyl linkages is described. The synthesis involves the reaction of dibromopropane with phenolic porphyrin to form omega-bromopropylporphyrin ether. This ether then reacts with another phenolic porphyrin to give the target compounds. The properties of the target compounds were confirmed by means of elemental analysis, UV-Vis., IR, and H-1 NMR spectroscopies. Their spectral properties and thermal stability were also studied.