详细信息
均相催化合成丙二醇甲醚的研究 ( EI收录)
Study on Homogeneous Catalytic Synthesis of Propylene Glycol Monomethyl Ether
文献类型:期刊文献
中文题名:均相催化合成丙二醇甲醚的研究
英文题名:Study on Homogeneous Catalytic Synthesis of Propylene Glycol Monomethyl Ether
作者:李涛[1];杨金根[1];严之光[1]
机构:[1]华东理工大学化学工程系
年份:1997
卷号:23
期号:1
起止页码:39
中文期刊名:华东理工大学学报(自然科学版)
外文期刊名:Journal of East China University of Science and Technology
收录:CSTPCD;;国家哲学社会科学学术期刊数据库;EI(收录号:1997123977155);Scopus;北大核心:【北大核心1996】;CSCD:【CSCD2011_2012】;
语种:中文
中文关键词:均相反应;丙二醇甲醚;催化;合成;催化剂
外文关键词:homogeneous reaction; methanol; propylene oxide; PM; kinetics
摘要:研究了甲醇与环氧丙烷在碱性催化剂TA存在下均相合成丙二醇甲醚的过程。在甲醇与环氧丙烷的配比为3∶1~5∶1(mol),催化剂使用量为0.5%~1.0%,反应温度60~120℃条件下,环氧丙烷转化率在99%以上,丙二醇甲醚的选择性在95%以上。对该反应的动力学研究表明,反应为一连串平行反应,并建立了相应的动力学模型。
A process of reacting propylene oxide with methanol using basic catalyst TA is investigated. Under the reaction conditions of the methanol/PO molar ratio between 3∶1 ̄5∶1,the temperature beteen 60 ̄120℃ and the amount of TA between 0.5% ̄1.0%, the conversion of propylene oxide is more than 99%, and the selectivity of PM is higher than 95%. The research of reaction kinetics shows that the reaction is a consecutive parallel one. Reaction kinetic model has been established.
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