文献类型：期刊文献

英文题名：Ortho-Functionalized Diaryliodonium Salts: Synthesis and Reactivity

作者：Chu, Lifeng[1,2,3];Wang, Limin[1,2,3];Han, Jianwei[1,2,3]

机构：[1]East China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Feringa Nobel Prize Scientist Joint Res Ctr, Dept Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China;[3]East China Univ Sci & Technol, Inst Fine Chem, Sch Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China

年份：2025

卷号：367

期号：22

外文期刊名：ADVANCED SYNTHESIS & CATALYSIS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:001582478200001)】；

基金：L.C., L.W. and J.H. are equally contributed to this work. Thework was supported by the National Nature ScienceFoundation of China (NSFC 22478117).

语种：英文

外文关键词：diaryliodonium salts; intramolecular interactions; ortho-functionalization

摘要：Hypervalent iodine reagents have attracted considerable attention in modern organic synthesis due to their low toxicity and versatile reactivity. Among them, ortho-functionalized diaryliodonium salts represent an important subclass, distinguished by their unique structural characteristics and reactivity. This review summarizes recent advances in the development of ortho-functionalized diaryliodonium reagents, with particular emphasis on the role of ortho-substituents as leaving groups or participanting moieties in reactions. Newly developed transformations are discussed alongside their mechanisms, highlighting the intramolecular interactions with the iodine(III) center.