文献类型：期刊文献

英文题名：Selective Oxidation of Alkylarenes to the Aromatic Ketones or Benzaldehydes with Water

作者：Zhang, Jin[1];Du, Jihong[1];Zhang, Chenyang[1];Liu, Kun[1];Yu, Feifei[1];Yuan, Yongkun[2];Duan, Baogen[2];Liu, Renhua[1,3]

机构：[1]East China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China;[2]Suzhou Yacoo Sci Co Ltd, Suzhou 215125, Jiangsu, Peoples R China;[3]Engn Res Ctr Pharmaceut Proc Chem, Shanghai 200237, Peoples R China

年份：2022

卷号：24

期号：5

起止页码：1152

外文期刊名：ORGANIC LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000779409800007)，CCR-EXPANDED(收录号:WOS:000779409800007)】；

语种：英文

摘要：Here a palladium-catalyzed oxidation method for converting alkylarenes into the aromatic ketones or benzaldehydes with water as the only oxygen donor is reported. This C-H bond oxidation functionalization does not require other oxidants and hydrogen acceptors, and H-2 is the only byproduct. The oxygen atom introduced into the products is confirmed to be from water by the MS analysis on the product of the O-18-labeled water reaction.