文献类型：期刊文献

英文题名：Selective Oxidation of 1-Tetralones to 1,2-Naphthoquinones with IBX and to 1,4-Naphthoquinones with Oxone? and 2-Iodobenzoic Acid

作者：Ren, Jiangmeng[1];Lu, Lei[1,2];Xu, Junchao[1,2];Yu, Tianyin[1,2];Zeng, Bu-Bing[1,2,3]

机构：[1]E China Univ Sci & Technol, Shanghai Key Lab New Drug Design, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China

年份：2015

卷号：47

期号：15

起止页码：2270

外文期刊名：SYNTHESIS-STUTTGART

收录：;EI(收录号：20152000842417);WOS:【SCI-EXPANDED(收录号:WOS:000358308300013)，CCR-EXPANDED(收录号:WOS:000358308300013)】；

基金：We thank the National Natural Science Foundation of China (21302053) for the generous financial support. We are also grateful for the financial support from Science and Technology Commission of Shanghai Municipality (14DZ1900102) the Fundamental Research Funds for the Central University (WY111307).

语种：英文

外文关键词：selective oxidation; IBX; 1; 2-naphthoquinones; 1; 4-naphthoquinones; hypervalent iodine reagents

摘要：The preparation of naphthoquinones by oxidation of 1-tetralone derivatives is reported. 1,2-Naphthoquinones were prepared by oxidation with IBX and 1,4-naphthoquinones were prepared by oxidation using Oxone((R)) and 2-iodobenzoic acid. The mechanistic pathways are also discussed.