文献类型：期刊文献

英文题名：Molecular simulation of miscibility of poly(2,6-dimethyl-1,4-phenylene ether)/poly(styrene-co-acrylonitrile) blend with the compatibilizer triblock terpolymer SBM

作者：Zhuang, Qixin[1]; Xue, Zhaojun[1]; Liu, Xiaoyun[1]; Yuan, Yongliang[1]; Han, Zhewen[1]

机构：[1] Key Laboratory for Specially Functional Polymers and Related Technology, East China University of Science and Technology, Ministry of Education, Shanghai 200237, China

年份：2011

卷号：32

期号：10

起止页码：1671

外文期刊名：Polymer Composites

收录：EI(收录号：20113914362785)

语种：英文

外文关键词：Ethers - Coarse-grained modeling - Molecular dynamics - Solubility - Chain length - Chains - Dissipative particle dynamics - Distribution functions - Automata theory - Esters

摘要：Polymer blend of poly(2,6-dimethyl-1,4-phenylene ether) (PPE) and poly(styrene-co-acrylonitrile) (SAN), which has broad commercial interest, has limited miscibility. A triblock terpolymer, polystyrene-block-polybutadiene- block-poly(methyl methacrylate) (SBM), is often used as compatibilizer to improve the miscibility of PPE/SAN. In this work, dissipative particle dynamics and molecular dynamics of Material Studio were used to study the essentials that influence miscibility of the blend systems, and then Flory-Huggins parameter π, radial distribution function (RDF) and morphologies are analyzed. It shows that the blends with more content of styrene in SAN (above 90 wt%), whose mass percentage is 60%, are best miscible. For the systems of PPE/SAN added with SBM, the miscibility increases and then decreases with the increase of SBM content. A longer chain of styrene (S) in SBM leads to wrapped structure of PMMA by PB, wrapped by PS, resulting in decrease of the miscibility. From studies and simulation of π and RDF, the best blend system for commercial and industrial use is the one with mass ratio of PPE/SAN/SBM 36/54/10, in which S content in SAN is above 90 wt%. For SBM, the ratio of chain length styrene (S)/butadiene (B) is lessthan 1, while B and M are the same in chain length. ? 2011 Society of Plastics Engineers.