文献类型：期刊文献

中文题名：亚酞菁的合成及其光谱性质

英文题名：Synthesis and Spectral Properties of Subphthalocyanines

作者：涂海洋[1];田禾[1]

机构：[1]华东理工大学精细化工研究所,上海200237

年份：2000

卷号：17

期号：2

起止页码：174

中文期刊名：应用化学

外文期刊名：Chinese Journal of Applied Chemistry

收录：CSTPCD;;北大核心:【北大核心1996】；CSCD:【CSCD2011_2012】；

基金：国家自然科学基金资助项目! ( 2 99860 0 1;2 983 615 0 )

语种：中文

中文关键词：亚酞菁;合成;邻苯二腈;光谱性质

外文关键词：subphthalocyanine,synthesis,phthalodinitrile,spectral property

摘要：Three axially bromo substituted subphthalocyanines(SubPc) were synthesized by reacting phthalodinitriles with boron tribromide. They have very good solubility in many common organic solvents. Their electronic absorption spectra and fluorescence emission spectra were measured. These SubPcs have a maximum absorption at 570 nm, which are blue shifted about 100 nm compared with corresponding phthalocyanine. When β position substituent is —OCH 2C(CH 3) 3 , the SubPc(2b) has fluorescence emission peaks at 415 and 608 nm. However, when there are two substituents at α position, the SubPc(2c) has only one fluorescence emission peak at 435 nm.
Three axially bromo substituted subphthalocyanines(SubPc) were synthesized by reacting phthalodinitriles with boron tribromide. They have very good solubility in many common organic solvents. Their electronic absorption spectra and fluorescence emission spectra were measured. These SubPcs have a maximum absorption at 570 nm, which are blue shifted about 100 nm compared with corresponding phthalocyanine. When β position substituent is —OCH 2C(CH 3) 3 , the SubPc(2b) has fluorescence emission peaks at 415 and 608 nm. However, when there are two substituents at α position, the SubPc(2c) has only one fluorescence emission peak at 435 nm.