文献类型：期刊文献

英文题名：Highly regio- and diastereoselective Cu-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes with B2pin2 and PhMe2Si-Bpin

作者：Zhao, Xianghu[1];Xu, Sixue[1];He, Jingjing[1];Zhou, Yao[1];Cao, Song[1]

机构：[1]ECUST, Sch Pharm, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China

年份：2019

卷号：6

期号：14

起止页码：2539

外文期刊名：ORGANIC CHEMISTRY FRONTIERS

收录：;EI(收录号：20192807179182);WOS:【SCI-EXPANDED(收录号:WOS:000477946500033)，CCR-EXPANDED(收录号:WOS:000477946500033)】；

基金：We are grateful for the financial support from the National Natural Science Foundation of China (Grant No. 21472043).

语种：英文

外文关键词：Catalysis

摘要：An efficient synthetic method for preparing trans-difluorocyclopropyl boronates and trans-difluorocyclopropyl silanes was easily achieved through a copper-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes with bis(pinacolato)diboron and silylboronate, respectively.