文献类型：期刊文献

英文题名：Effects of synthetic conditions on the structure and electrical properties of polyaniline nanofibers

作者：Su, Chang[1]; Wang, Gengchao[1]; Huang, Farong[1]; Li, Xingwei[1]

机构：[1]E China Univ Sci & Technol, Sch Mat Sci & Engn, Key Lab Ultrafine Mat, Minist Educ, Shanghai 200237, Peoples R China

年份：2008

卷号：43

期号：1

起止页码：197

外文期刊名：JOURNAL OF MATERIALS SCIENCE

收录：;EI(收录号：20075010970530);WOS:【SCI-EXPANDED(收录号:WOS:000251371500025)】；

语种：英文

外文关键词：Electric properties - Fourier transform infrared spectroscopy - Hydrochloric acid - Polyaniline - Synthesis (chemical) - Transmission electron microscopy

摘要：Polyaniline nanofibers were synthesized by interfacial polymerization in the presence of hydrochloric acid (HClO4). The effects of the molar ratio of ammonium persulfate (APS) to aniline (ANI) (represented by [APS]/[ANI] ratio) and HClO4 concentration on the morphology, chain structures, and electrical properties of the polyaniline (PANI) were investigated to understand the formation of nanofibers. The structure and properties of the resulted PANI were characterized with FTIR, UV-Vis, TEM, XRD, and conductivity in detail. The results showed that low [APS]/[ANI] ratio (<= 1/4) and high HClO4 concentration (>= 1000 mol/m(3)) were benefit to the preparation of uniform PANI nanofibers with low content of phenazine-like units and ANI oligomers, and high conductivity.