文献类型：期刊文献

中文题名：铁酸镁在苯酚过氧化氢羟基化反应中的催化性能

英文题名：Catalytic Performance of Magnesium Ferrite for Hydroxylation of Phenol with Hydrogen Peroxide

作者：张淳[1,2];熊春荣[3];隆仲华[4];朱中南[1]

机构：[1]华东理工大学化工学院;[2]上海高桥石油化工公司高桥化工厂,上海200137;[3]中国石油化工集团公司上海石油化工研究院;[4]上海高桥石油化工公司高桥化工厂

年份：2000

卷号：21

期号：4

起止页码：372

中文期刊名：催化学报

收录：CSTPCD;;Scopus;北大核心:【北大核心1996】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：铁酸镁;苯酚;过氧化氢;羟基化;苯二酚;催化性能

外文关键词：magnesium ferrite, phenol, hydrogen peroxide, hydroxylation, diphenol

摘要：A novel catalyst, MgFe 2O 4, for hydroxylation of phenol with hydrogen peroxide was synthesized via coprecipitation method from an aqueous solution containing Fe(NO 3) 3·9H 2O and Mg(NO 3) 2·6H 2O with ammonia. The X ray diffraction peaks of the catalyst show that the as prepared sample has engendered MgFe 2O 4 crystal with spinel structure, which is also confirmed by its IR spectrum. In the hydroxylation of phenol with hydrogen peroxide, MgFe 2O 4 catalyst exhibited high activity after a short induction period. In particular, the addition of a little amount of acetic acid in the reaction liquid can effectively shorten the induction period. Under the same reaction conditions, the diphenol selectivity over MgFe 2O 4 is higher than that over TS 1, furthermore, the reaction time is shortened greatly. The experimental phenomena can be explained by the free radical mechanism.
A novel catalyst, MgFe 2O 4, for hydroxylation of phenol with hydrogen peroxide was synthesized via coprecipitation method from an aqueous solution containing Fe(NO 3) 3·9H 2O and Mg(NO 3) 2·6H 2O with ammonia. The X ray diffraction peaks of the catalyst show that the as prepared sample has engendered MgFe 2O 4 crystal with spinel structure, which is also confirmed by its IR spectrum. In the hydroxylation of phenol with hydrogen peroxide, MgFe 2O 4 catalyst exhibited high activity after a short induction period. In particular, the addition of a little amount of acetic acid in the reaction liquid can effectively shorten the induction period. Under the same reaction conditions, the diphenol selectivity over MgFe 2O 4 is higher than that over TS 1, furthermore, the reaction time is shortened greatly. The experimental phenomena can be explained by the free radical mechanism.