文献类型：期刊文献

英文题名：Preparation and characterization of TiO₂ photocatalysts by Fe³⁺ doping together with Au deposition for the degradation of organic pollutants

作者：Wu, Yongmei;Zhang, Jinlong[1];Xiao, Ling;Chen, Feng

机构：[1]E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2009

卷号：88

期号：3-4

起止页码：525

外文期刊名：APPLIED CATALYSIS B-ENVIRONMENTAL

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000266513400033)】；

基金：This work has been supported by Shanghai Pujiang Programme (05PJ14033): Shanghai Nanotechnology Promotion Centre (0752/001), Nationall Nature Science Foundation of China (20577009, 20773039), National Basic Research Program of China (973 Program, 2007CB613306,2004CB719500) and the Ministry of Science and Technology of China (2006AA06Z379,2006DFA52710).

语种：英文

外文关键词：Titania; Fe3+ doped; Au deposited; Photodegradation; Synergistic effect

摘要：Fe3+ doped TiO2 deposited with Au (Au/Fe-TiO2) was successfully prepared with an attempt to extend light absorption of TiO2 into the visible region and reduce the rapid recombination of electrons and holes. The samples were characterized by X-ray diffraction (XRD), N-2 physical adsorption, Raman spectroscopy, atomic absorption flame emission spectroscopy (AAS), UV-vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy (XPS), and photoluminescence (PL) spectra. The photocatalytic activities of the samples were evaluated for the degradation of 2,4-chlorophenol in aqueous solutions under visible light (lambda > 420 nm) and UV light irradiation. The results of XRD, XPS and high-resolution transmission electron microscopy (HRTEM) analysis indicated that Fe3+ substituted for Ti3+ in the lattice of TiO2, Au existed as Au-0 on the surface of the photocatalyst and the mean particle size of Au was 8 nm. Diffuse reflectance measurements showed an extension of light absorption into the visible region for Au/Fe-TiO2, and PL analysis indicated that the electron-hole recombination rate has been effectively inhibited when Au deposited on the surface of Fe-doped TiO2, Compared with Fe doped TiO2 sample and Au deposited TiO2 sample, the Au/Fe-TiO2 photocatalyst exhibited excellent visible light and UV light activity and the synergistic effects of Fe3+ and Au was responsible for improving the photocatalytic activity. (C) 2008 Elsevier B.V. All rights reserved.