文献类型：期刊文献

英文题名：Pd(0)-Catalyzed Iodoalkynation of Norbornene Scaffolds: The Remarkable Solvent Effect on Reaction Pathway

作者：Liu, Hui[1];Chen, Chen[1];Wang, Limin[1];Tong, Xiaofeng[1]

机构：[1]E China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China

年份：2011

卷号：13

期号：19

起止页码：5072

外文期刊名：ORGANIC LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000295313900025)】；

基金：The financial support from NSFC (No. 21002025), the Fundamental Research Funds for the Central Universities, Shanghai Rising-Star Program (11QA1401700), and Specialized Research Fund for the Doctoral Program of Higher Education (20100074120014) is highly appreciated.

语种：英文

摘要：A palladium-catalyzed iodoalkynation of norbornene has been realized with the use of alkynyl iodides 1, which is found to be strongly solvent-dependent. MeCN favors 1,7-iodoalkylation product 3 while CCl4 leads to 1,2-iodoalkylation product 4.