文献类型：专利

英文题名：New nickel coordination compound which is blend of 5-isopropyl-2-hydroxy-1,3-m-phthalaldehyde, 5-tertiary butyl-2-hydroxy-1,3-m-phthalaldehyde and 1,3-diethylaminoethyl-2-hydroxypropane for use in magnetic material field

作者：YANG Y;WANG C;XIE Y;HE C

机构：[1]UNIV EAST CHINA SCI&TECHNOLOGY

申请号：CN102174062-A

申请日：2011-03-02

公开日：2011-09-07

语种：英文

收录：DERWENT

摘要：NOVELTY - A nickel coordination compound, which is prepared by blending 5-isopropyl-2-hydroxy-1,3-m-phthalaldehyde, 5-tert-butyl-2-hydroxy-1,3-m-phthalaldehyde and 1,3-diethylaminoethyl-2-hydroxypropane, is new. USE - A nickel coordination compound for use in magnetic material field. ADVANTAGE - The nickel coordination compound is prepared by a method where the different ligands and metal salts in the coordinating process are placed on two ends of the H-type tube so that the diffusing is slower and more uniform, and the crystal of the coordination compound is convenient to culture and generate. Further, the reaction is performed at the normal temperature and normal pressure, with mild condition, high yield and excellent repeatability. DETAILED DESCRIPTION - A nickel coordination compound of formula ((Ni4(L1)3(L2)(biam)2(O)2(N3)2)(CH3OH)5)8, which is prepared by blending 5-isopropyl-2-hydroxy-1,3-m-phthalaldehyde, 5-tertiary butyl-2-hydroxy-1,3-m-phthalaldehyde and 1,3-diethylaminoethyl-2-hydroxypropane, is new. L1=5-isopropyl-2-hydroxy-1,3-m-phthalaldehyde; L2=5-tert-butyl-2-hydroxy-1,3-m-phthalaldehyde; and biam=1,3-diethylaminoethyl-2-hydroxypropane. An INDEPENDENT CLAIM is included for a method for preparing the nickel coordination compound (I).