文献类型：期刊文献

英文题名：The Reaction Kinetics of a Fischer-Tropsch Synthesis Over a Commercial Eggshell Co/SiO2 Catalyst

作者：Lu, F.[1];Zhang, H.[1];Ying, W.[1];Fang, D.[1]

机构：[1]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2010

卷号：28

期号：18

起止页码：1834

外文期刊名：PETROLEUM SCIENCE AND TECHNOLOGY

收录：;EI(收录号：20104313329957);WOS:【SCI-EXPANDED(收录号:WOS:000283064900002)】；

基金：The authors gratefully acknowledge the financial support from China Petrochemical program (No. 107035) and the Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT; IRT0620).

语种：英文

外文关键词：eggshell Co; SiO2 catalyst; Fischer-Tropsch synthesis; hydrocarbon kinetics

摘要：The comprehensive kinetic model of Fischer-Tropsch synthesis over a commercial eggshell Co/SiO2 catalyst in a fixed-bed reactor was investigated experimentally. This model was expressed in the combination of kinetic rate of CO consumption and the equation of the growth probability factor was obtained. Through parameter evaluation and optimization, both the rate of CO consumption was given and the equation of a was obtained. It was also proved that the proposed model could predict the kinetic rate of CO consumption and the product distributions well. The appropriate operating conditions for this catalyst were concluded by the model and they were in good agreement with the results in the industrial pilot-scale research.