文献类型：期刊文献

英文题名：Reversible switching of a supramolecular morphology driven by an amphiphilic bistable [2] rotaxane

作者：Cao, Zhan-Qi[1,2,3];Wang, Yi-Chuan[1,2];Zou, Ai-Hua[1,2];London, Gabor[4];Zhang, Qi[1,2];Gao, Chuan[1,2];Qu, Da-Hui[1,2]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China;[3]Henan Agr Univ, Coll Sci, Zhengzhou 450002, Henan, Peoples R China;[4]Hungarian Acad Sci, Res Ctr Nat Sci, Inst Organ Chem, Magyar Tudosok Korutja 2, H-1117 Budapest, Hungary

年份：2017

卷号：53

期号：62

起止页码：8683

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000406669000012)】；

基金：We thank the NSFC/China (21672060 and 21421004), the Fundamental Research Funds for the Central Universities (WJ1616011, WJ1213007, and 222201717003), and the Programme of Introducing Talents of Discipline to Universities (B16017).

语种：英文

摘要：An acid/base responsive amphiphilic [2] rotaxane switch containing a hydrophilic macrocycle component and a hydrophobic terminal bulky group was prepared and characterized. The morphology of the supramolecular assemblies formed by the rotaxanes could be switched between spherical vesicles and worm-like micelles using acid/base stimuli, as confirmed by transmission electron microscopy (TEM).