文献类型：期刊文献

英文题名：Ruthenium Trichloride Catalyzed Highly Efficient Deoximation of Oximes to the Carbonyl Compounds and Nitriles without Acceptors

作者：Liu, Yuxiao[1];Yang, Na[1];Chu, Changhu[1];Liu, Renhua[1]

机构：[1]E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

年份：2015

卷号：33

期号：9

起止页码：1011

外文期刊名：CHINESE JOURNAL OF CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000362839100002)，CCR-EXPANDED(收录号:WOS:000362839100002)】；

基金：Financial support from the National Natural Science Foundation of China (No. 21072055) and the National High Technology Research and Development Program of China (863 Program) (No. 2008AA06Z306).

语种：英文

外文关键词：deoximation; ruthenium trichloride; hydrolysis; acceptor-free

摘要：An acceptor-free catalysis protocol for the deoximation of ketoximes and aldoximes using RuCl3 as the catalyst has been developed. Under the optimized conditions, various oximes were converted to ketones and nitriles with excellent isolated yields.