文献类型：期刊文献

英文题名：The role of MgO in the formation of surface active phases of CoMo/Al₂O₃-MgO catalysts for hydrodesulfurization of dibenzothiophene

作者：Wu, Libao[1];Jiao, Dongmei[1,2];Wang, Jin-an[3];Chen, Lifang[3];Cao, Fahai[1]

机构：[1]E China Univ Sci & Technol, Sch Chem Engn, Shanghai 200237, Peoples R China;[2]Luoyang Petrochem Complex SINOPEC, Luoyang 471000, Peoples R China;[3]Inst Politecn Nacl, ESIQIE, Mexico City 07738, DF, Mexico

年份：2009

卷号：11

期号：4

起止页码：302

外文期刊名：CATALYSIS COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000272979900017)】；

基金：The authors would like to express their gratitude to the financial support from Luoyang Petrochemical Company of SINOPEC, China.

语种：英文

外文关键词：Al2O3-MgO; Hydrodesulfurization; Small cluster

摘要：A series of CoMo/Al2O3-MgO-x (x = [MgO/(Al2O3 + MgO)], weight ratio) catalysts were prepared by incipient wetness impregnation method with urea as chelating agent. The characterization results of UV-vis diffuse reflectance spectroscopy and Raman spectroscopy showed that Mo and Co species were highly dispersed in small clusters. Introduction of a proper amount of MgO into Al2O3 support not only induced new active forms of Mo species formed on the surface of the catalysts but also successfully inhibited the formation of inactive CoAl2O4 or Co3O4 phases, thus significantly improving the hydrodesulfurization activity. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.