文献类型：期刊文献

英文题名：Study on CO2 gasification characteristics of pyrolysis char from pinewood block and pellet

作者：Wang, Tian[1];Tang, Longfei[1];Raheem, Abdul[1];Chen, Xueli[1];Wang, Fuchen[1]

机构：[1]East China Univ Sci & Technol, Shanghai Engn Res Ctr Coal Gasificat, POB 272, Shanghai 200237, Peoples R China

年份：2023

卷号：13

期号：11

起止页码：9889

外文期刊名：BIOMASS CONVERSION AND BIOREFINERY

收录：;EI(收录号：20214111013296);WOS:【SCI-EXPANDED(收录号:WOS:000706047600001)】；

基金：This work was supported by the social development science and technology tackling project of 2020 "Scientific and Innovative Action Plan of Shanghai" (20dz1203300).

语种：英文

外文关键词：Pelletization; CO2 gasification; Reactivity index; Kinetic model; Char structure

摘要：Gasification reaction characteristics of pinewood block char (PW char) and pinewood pellet char (PWP char) were studied by analyzing CO (a component of syngas) generating rate at different temperatures (900, 1000, 1100 degrees C), respectively. The results demonstrated that the char with smaller size (15 mm) showed higher reactivity index than bigger size (30 mm). Increase in temperature (900 - 1100 degrees C) improved reaction rate and likely compensated for the diffusion resistance for larger particle. The reaction rate of PW char could be considered a constant varying from 10 to 90% carbon conversion when temperature was less than 1000 degrees C, and the nucleation and growth model with two close nucleation speed stages confirmed it. The parameter with great influence on PW char and PWP char gasification was porosity, followed by pore structure. Similar porosity between PW char and PWP char resulted in similar carbon conversion time, while more smaller pores (2-13.5 nm) of PW char led to high specific surface area (SSA) then increased higher gasification reactivity. These results are useful for gasification materials selection. Specifically of interest is adjustment of gasifier and bed layer movement to better match properties of materials.