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Ytterbium pentafluorobenzoate as a novel fluorous Lewis acid catalyst in the synthesis of 2,4-disubstituted quinolines  ( SCI-EXPANDED收录)  

文献类型:期刊文献

英文题名:Ytterbium pentafluorobenzoate as a novel fluorous Lewis acid catalyst in the synthesis of 2,4-disubstituted quinolines

作者:Tang, Jun;Wang, Limin[1];Mao, Dan;Wang, Wenbo;Zhang, Liang;Wu, Shengying;Xie, Yongshu

机构:[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份:2011

卷号:67

期号:44

起止页码:8465

外文期刊名:TETRAHEDRON

收录:;WOS:【SCI-EXPANDED(收录号:WOS:000295957000005),CCR-EXPANDED(收录号:WOS:000295957000005)】;

基金:This research was financially supported by the National Nature Science Foundation of China (20672035) and Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.

语种:英文

外文关键词:Ytterbium pentafluorobenzoate; Lewis acid; Rare earth metal; Quinolines; One-pot reaction

摘要:A series of simple, efficient, stable and recoverable rare earth metal pentafluorobenzoates [RE(Pfb)(3)] have been synthesized for the first time. A highly efficient and environmentally friendly synthesis of 2,4-disubstituted quinolines catalyzed by Yb(Pfb)(3) via one-pot reaction of aldehydes, alkynes and amines under solvent-free conditions has been explored. (C) 2011 Elsevier Ltd. All rights reserved.

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