文献类型：期刊文献

英文题名：Hydrogen Production by the Catalytic Reforming of Volatile from Biomass Pyrolysis over a Bimetallic Catalyst

作者：Zhang, Y.[1,2];Li, W.[3];Zhang, S.[1];Xu, Q.[1];Yan, Y.[1]

机构：[1]E China Univ Sci & Technol, Key Lab Coal Gasificat & Energy Chem Engn, Minist Educ, Shanghai 200237, Peoples R China;[2]Liaoning Tech Univ, Huludao, Peoples R China;[3]Univ Sci & Technol China, Anhui Key Lab Biomass Clean Energy, Hefei 230026, Peoples R China

年份：2013

卷号：35

期号：21

起止页码：1975

外文期刊名：ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS

收录：;EI(收录号：20134016794589);WOS:【SCI-EXPANDED(收录号:WOS:000323999400002)】；

基金：This research project was financially supported by the National Basic Research Program of China (973) "Hydrogen Production via Bio-oil's Reforming: Reaction Mechanism and Fundamental Principles" (2007CB210206).

语种：英文

外文关键词：bimetallic catalyst; biomass; catalytic reforming; hydrogen production; pyrolysis

摘要：Ni-Co/-Al2O3, Ni/-Al2O3, Co/-Al2O3, mechanical mixed Ni/-Al2O3, and Co/-Al2O3 catalyst (another name is Ni/-Al2O3|Co/-Al2O3) were prepared by the wet impregnation method, and the catalytic performance for hydrogen production by catalytic reforming of volatile from biomass pyrolysis over the four catalysts was compared under the condition of different temperatures and weight hourly space velocity. The experimental results show that the catalytic performance of the four catalysts from high to low is Ni-Co/-Al2O3 > Co/-Al2O3 > Ni/-Al2O3|Co/-Al2O3 > Ni/-Al2O3 within the studied temperature and weight hourly space velocity scope. Hydrogen selectivity of 94.83% and hydrogen yield of 120.81 g/kg biomass (dry basis) were obtained over Ni-Co/-Al2O3 under the condition of catalytic reforming temperature of 825 degrees C and weight hourly space velocity of 0.71 h(-1).