详细信息
文献类型:期刊文献
中文题名:IPDI的NMR数据解析
英文题名:Characterization of Isophrone Diisocyanate (IPDI) by NMR Spectroscopy
作者:汪雷敏[1];潘铁英[1];史新梅[1];周丽芳[1];吴翔[1];党晓容[2];袁荞龙[2];王得宁[2]
机构:[1]华东理工大学分析测试中心,上海200237;[2]华东理工大学材料科学与工程学院,上海200237
年份:2005
卷号:22
期号:1
起止页码:79
中文期刊名:波谱学杂志
外文期刊名:Chinese Journal of Magnetic Resonance
收录:CSTPCD;;北大核心:【北大核心2004】;CSCD:【CSCD2011_2012】;PubMed;
基金:国家自然科学基金资助项目(50073005).
语种:中文
中文关键词:核磁共振;异氟尔酮二异氰酸酯;异构体;热稳定性
外文关键词:NMR, isophrone diisocyanate, isomer, heat-stability
摘要:用NMR对异氟尔酮二异氰酸酯(IPDI)的两种立体异构体进行结构表征, 包括1H、13C、DEPT135、HMBC、HMQC谱, 并详细解析图谱. 此外对这两种异构体在不同温度下的稳定性进行了研究.
The two isomers of isophrone diisocyanate (IPDI) were characterized by ~1H and ~13C NMR spectroscopy The stability of the compounds at different temperatures was studied by ~13C NMR The results show that the chemical shift and the peak area of the two isomers didn't change at 40~80 ℃ so that it may be concluded that the two isomers were stable in this temperature range
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