文献类型：期刊文献

中文题名：锐钛型二氧化钛/水悬浮体的流变性研究

英文题名：Rheological Behavior of TiO_2/Water Suspensions

作者：杨化桂[1];高丕英[1];古宏晨[1];方图南[1]

机构：[1]华东理工大学技术化学物理研究所,上海200237

年份：2000

卷号：15

期号：3

起止页码：431

中文期刊名：无机材料学报

外文期刊名：Journal of Inorganic Materials

收录：CSTPCD;;EI(收录号：2001025401074);Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000087903300009)】；北大核心:【北大核心1996】；CSCD:【CSCD2011_2012】；

基金：国家自然科学基金!29636010

语种：中文

中文关键词：二氧化钛;剪切粘度;粒度;悬浮体;流变性;锐钛型

外文关键词：TiO_2, shear viscosity; yield stress; particle size distribution; volume fraction, rheological properties of suspension

摘要：本文用流变学的方法在Brabender流变仪上研究了不同因素对二氧化钛悬浮体流变性的影响．在同一体积分率下，与粒度分布宽的颗粒形成的悬浮体相比，粒度分布窄的颗粒形成的悬浮体其屈服应力和稳态剪切粘度较大；在二氧化钛体积分率很小时，悬浮体呈牛顿性；当体积分率大于一定值时，悬浮体具有零剪切粘度和剪切稀化特征；当其大于一临界值时，存在屈服应力并有强烈的剪切稀化行为．悬浮体粘度服从广义Quemada流变方程．在温度＜40℃时，温度升高使粘度和屈服应力降低；在温度＞40℃时，温度升高，屈服应力升高，而粘度在不同的剪切速率范围内有复杂的行为，这可用分散介质中颗粒的碰撞理论来解释．
The rheological properties of TiO2/water suspensions were examined by means of Brabender rheometer with rheological method. It was observed that yield stress and steady shear viscosity of TiOa/water suspensions with narrow PSD is higher than those of TiO2/water suspensions with wide PSD. When volume fraction of particle di is very low, the suspension exhibits Newtonian behavior. All tested pastes exhibit shear-thinning behavior when volume fraction of particle di is higher than a certain value; when di beyond a critical value, the pastes have yield stress and exhibit more obvious shear-thinning behavior. The shear viscosity of TiO2/water suspensions follows a generalized Quemada model and parameters were obtained by simulating. When the temperature is below 40℃, the shear viscosity and yield stress decrease with the increasing of temperature; when the temperature is higher than 40℃, yield stress increases with the increasing of tepsperature while shear viscosity exhibits complex behavior. The temperature dependence of shear viscosity and yield stress can be explained by collision theory of fine particles in suspending mediums.