文献类型：期刊文献

英文题名：(Ni/MgAl2O4)@SiO2core-shell catalyst with high coke-resistance for the dry reforming of methane

作者：Wang, Yousen[1];Fang, Qiong[1];Shen, Weihua[1];Zhu, Zhiqing[1];Fang, Yunjin[1]

机构：[1]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2018

卷号：125

期号：1

起止页码：127

外文期刊名：REACTION KINETICS MECHANISMS AND CATALYSIS

收录：;EI(收录号：20181404974180);WOS:【SCI-EXPANDED(收录号:WOS:000443009300011)】；

基金：This work is supported by the National Natural Science Foundation of China (Project No. 21576083), sponsored by Shanghai Pujiang Program (No. 14PJ1402400), and supported by the Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure(No. SKL201510SIC).

语种：英文

外文关键词：Dry reforming; Methane; Coke-resistance; Core-shell; Nickel

摘要：A novel core-shell catalyst as [(Ni/MgAl2O4)@SiO2] was successfully prepared by three steps. First, the support was prepared, then 10 wt% Ni was loaded upon the support by the wetness incepting impregnation method; finally, the catalyst was coated with mesoporous silica. Two supports with different sizes were synthesized by homogeneous precipitation method and solution combustion method, respectively. Based on different supports, two series of catalysts with the characteristics of same components and different particle diameters were obtained. All catalysts were characterized by X-ray diffraction, transmission electron microscopy, N-2-physisorption and thermal gravimetric analyzer to measure the crystallinity, morphology, surface structure and carbon deposition. The results shown that core- shell catalysts [(Ni/MgAl2O4)@SiO2] had better coke-resistance and stability than the uncoated catalysts (Ni/MgAl2O4). Therefore, core-shell catalyst coated by silica exhibited better performance in dry reforming of methane.