文献类型：期刊文献

英文题名：Synthesis and characterization of Palladium(II) complexes of chiral chelating NHC-N donor hybrid ligands

作者：Wang, Wenfeng[1,2];Zhang, Tao[1,2];Wang, Feijun[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2011

卷号：67

期号：8

起止页码：1523

外文期刊名：TETRAHEDRON

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000287435900001)】；

基金：We thank the Shanghai Municipal Committee of Science and Technology (08dj1400100-2), National Basic Research Program of China (973)-2009CB825300, and the National Natural Science Foundation of China for financial support (20472096, 20872162, 20672127, 20821002, and 20732008).

语种：英文

摘要：A new class of palladium(II) complexes of chelating NHC-N donor hybrid ligands, such as NHC-sulfonamide (6), NHC-phenoxyimine (11), NHC-phenylimine (14), and NHC-amine (15) have been successfully synthesized in modest yields from 1,1'-binaphthyl-2,2'-diamine (BINAM). These complexes have been characterized by all the spectroscopic data, and the structures of 6, 11, and 14 were also confirmed by single-crystal X-ray diffraction studies, exhibiting a tridentate chelating motif around the palladium center. (C) 2011 Elsevier Ltd. All rights reserved.