文献类型：期刊文献

英文题名：Template-Free Synthesis of Mesoporous Polymers for Highly Selective Enrichment of Glycopeptides

作者：Jin, Tian[1,2];Xiong, Zhichao[1,2,5];Zhu, Xiang[1,2,3];Mehio, Nada[4];Chen, Yajing[1,2];Hu, Jun[1,2];Zhang, Weibing[1,2];Zou, Hanfa[5];Liu, Honglai[1,2];Dai, Sheng[4]

机构：[1]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China;[3]Tech Univ Dresden, Dept Chem & Food Chem, D-01062 Dresden, Germany;[4]Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA;[5]Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian, Peoples R China

年份：2015

卷号：4

期号：5

起止页码：570

外文期刊名：ACS MACRO LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000355066600020)】；

基金：This work is supported by the National Basic Research Program of China (Grant 2013CB733501), the National Natural Science Foundation of China (Grants 91334203, 21376074, and 21321064), the 111 Project of Ministry of Education of China (Grant B08021), and the Fundamental Research Funds for the Central Universities. N.M. and S.D. were supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geo-sciences, and Biosciences Division.

语种：英文

摘要：A facile template-free strategy for the synthesis of mesoporous phenolic polymers with attractive porosities, nitrogen-containing functionalities, and intrinsic hydrophilic skeletons is presented. The resultant polymer has a high BET surface area (548 m(2) g(-1)) and mesopore size (13 nm) and exhibits superior glycopeptide-capturing performance, thus, revealing the potential application of mesoporous polymers in highly selective glycopeptide enrichment. This general capture protocol may open up new opportunities for the development of glycoproteomes.