文献类型：期刊文献

英文题名：Development of Pd catalyzed asymmetric additions in the last five years

作者：Sun, Yin-wei[1,2];Zhu, Peng-long[1,2];Xu, Qin[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2013

卷号：3

期号：10

起止页码：3153

外文期刊名：RSC ADVANCES

收录：;EI(收录号：20130816036020);WOS:【SCI-EXPANDED(收录号:WOS:000314701800001)】；

基金：We thank the Shanghai Municipal Committee of Science and Technology (11JC1402600), National Basic Research Program of China (973)-2009CB825300, the Fundamental Research Funds for the Central Universities and the National Natural Science Foundation of China for financial support (21072206, 20472096, 20872162, 20672127, 21121062 and 20732008).

语种：英文

外文关键词：Palladium compounds - Stereoselectivity - Carbon

摘要：Recent developments on Pd complex-catalyzed asymmetric additions in the last five years have been presented in this context. As can be seen from this paper, lots of Pd complex-catalyzed asymmetric reactions have been reported in last five years. The Pd-catalyzed asymmetric additions of C=X bonds (X = C, O, N) with various nucleophiles including boronic acids are very efficient and highly stereoselective under mild conditions. These type reactions have been developed into well-established methods for the stereoselective construction of carbon-carbon and carbon-heteroatom bonds in organic synthesis.