文献类型：期刊文献

中文题名：用中性溶液法制备硅基太阳能电池用低反射涂层

英文题名：Preparation of Antireflective Film on Borosilicate Glass for Solar Energy by Neurtral Solution Method

作者：方园[1];宋鹂[2];张金朝[2];陈奇[1,2]

机构：[1]华东理工大学材料科学与工程学院,超细材料制备与应用教育部重点实验室,上海市先进聚合物材料重点实验室,上海200237;[2]华东理工大学材料科学与工程学院无机材料系,上海200237

年份：2011

卷号：37

期号：1

起止页码：45

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;Scopus;北大核心:【北大核心2008】；CSCD:【CSCD2011_2012】；

基金：上海市重点学科建设项目(B502);重点实验室项目(08DZ2230500)

语种：中文

中文关键词：中性溶液法;硼硅酸盐玻璃;太阳能;低反射;耐候性

外文关键词：neutral solution etching; borosilicate glass; solar energy; antireflective; weatherability

摘要：用中性溶液法在硼硅酸盐玻璃片上制备了低反射涂层,并在Na2HPO4和AlCl3组成的浸涂液中于95°C条件下恒温浸泡6 h,结果表明硼硅酸盐玻璃片在400-900 nm波长内的平均透过率由原来的91.97%提高至98.97%,平均反射率降低至1.41%,中心波长处反射率仅为0.85%。为提高涂膜的耐候性,以低质量分数的十三氟辛基三乙氧基硅烷（FAS）对涂层样品进行表面处理。抗酸性测试结果表明：经w=0.3%的FAS溶液处理后的低反射涂层在1 mol/L盐酸中连续侵蚀7 d后,透过率平均值仍达到95.44%。说明经过FAS处理后,低反射涂层的耐候性能得到提高,使用寿命延长。
The antireflective（AR） film on borosilicate glass was prepared by a neutral solution etching process in this work.After immersing in the neutral solution composed of Na2HPO4 and AlCl3 at 95（°C） for 6 h,the average optical transmittance（400-900 nm） of the glass increased from 91.97% to 98.97%,the average reflectivity decreased to 1.41% and the reflectivity was only 0.85% at center wavelength.In order to improve the weatherability of the sample,the coated sample was retreated by perfluorooctyltriethoxysilane（FAS） at a low concentration.The resistant test of the sample etching in（1 mol/L） HCl solution for 7 d showed that the average optical transmittance（400-900 nm） of the glass retreated by FAS was still 95.44%.It means that the weatherability of the coated samples is improved by retreating with FAS and the using life of a AR film on borosilicate glass can be prolonged.