文献类型：期刊文献

英文题名：A partially graphitic carbon catalyst for aerobic oxidation of cyclohexane

作者：Guo, Yong[1];Ying, Ting[1];Liu, Xiaohui[1];Shi, Bianfang[2];Wang, Yanqin[1]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Res Inst Ind Catalysis, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Sch Chem Engn, Instrument Anal Ctr 985, Shanghai 200237, Peoples R China

年份：2019

卷号：479

起止页码：170

外文期刊名：MOLECULAR CATALYSIS

收录：;EI(收录号：20193807456712);WOS:【SCI-EXPANDED(收录号:WOS:000491683500017)】；

基金：This work was supported financially by the NSFC of China (Nos. 21832002, 21808063, 21872050), the Fundamental Research Funds for the Central Universities (222201718003) and the Science and Technology Commission of Shanghai Municipality (10dz2220500).

语种：英文

外文关键词：Partially graphitic carbon; Aerobic oxidation; Cyclohexane; KA oil

摘要：A novel partially graphitic carbon catalyst was developed and used in the aerobic oxidation of cyclohexane to KA oil (cyclohexanol A= and K= cyclohexanone) in liquid phase. Excellent catalytic performance was achieved and the conversion of cyclohexane reached 54.8% with a high selectivity of 44.4% to KA oil at 125 degrees C for 8 h. The characterizations and control experiment results shows that the co-existence of the graphitic structure and amorphous part is crucial to this excellent performance.