文献类型：期刊文献

英文题名：Controlled synthesis of hierarchical polyaniline nanowires/ordered bimodal mesoporous carbon nanocomposites with high surface area for supercapacitor electrodes

作者：Yan, Yanfang[1];Cheng, Qilin[1,2];Zhu, Zhengju[1];Pavlinek, Vladimir[2];Saha, Petr[2];Li, Chunzhong[1]

机构：[1]E China Univ Sci & Technol, Sch Mat Sci & Engn, Minist Educ, Key Lab Ultrafine Mat, Shanghai 200237, Peoples R China;[2]Tomas Bata Univ Zlin, Ctr Polymer, Ctr Polymer Syst, Zlin 76001, Czech Republic

年份：2013

卷号：240

起止页码：544

外文期刊名：JOURNAL OF POWER SOURCES

收录：;EI(收录号：20132116358612);WOS:【SCI-EXPANDED(收录号:WOS:000321803700067)】；

基金：This work was supported by the National Natural Science Foundation of China (20925621, 21236003, 21206043), the Shanghai Pujiang Program (12PJ1401900), the Fundamental Research Funds for the Central Universities and the Project sponsored by SRF for ROCS, SEM.

语种：英文

外文关键词：Polyaniline nanowires; Ordered bimodal mesoporous carbon; Nanocomposite; Electrochemical properties

摘要：A facile strategy is developed for the synthesis of hierarchical polyaniline nanowires/ordered bimodal mesoporous carbon (PANI/OBMC) composites via chemical oxidative polymerization. Structural and morphological characterizations indicate that the polyaniline nanowire arrays with 20-30 nm diameters are grown on the surface of the OBMC. The bimodal pore distribution and hierarchical nanostructure endow the PANI/OBMC composite with high surface area of 599 m(2) g(-1). Electrochemical performance of the hierarchical PANI/OBMC composite as supercapacitor electrode materials has been evaluated by cyclic voltammetry and galvanostatic charge-discharge techniques. The hierarchical composite with 60 wt% PANI possesses the highest specific capacitance of 517 F g(-1) and outstanding cycling stability with a capacitance retention of 91.5% after 1000 cycles. The coexistence of primary mesopores and abundant small mesopores is in favor of the fast penetration of electrolyte and the unique hierarchical structure facilitates the ion diffusion and shortens the charge transfer distance, which lead to superior electrochemical performance of PANI/OBMC-60%. (C) 2013 Elsevier B.V. All rights reserved.