文献类型：期刊文献

英文题名：Core-shell Co@CoO catalysts for the hydroformylation of olefins

作者：Xu, Wen[1];Ma, Yuan[1];Wei, Xinjia[1];Gong, Honghui[1];Zhao, Xiuge[1];Qin, Yuxi[1];Peng, Qingpo[1];Hou, Zhenshan[1]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Res Inst Ind Catalysis, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China

年份：2022

卷号：46

期号：32

起止页码：15712

外文期刊名：NEW JOURNAL OF CHEMISTRY

收录：;EI(收录号：20223112529676);WOS:【SCI-EXPANDED(收录号:WOS:000832642300001)】；

基金：The authors acknowledge the support from the National Natural Science Foundation of China (21773061, 21978095) and the Innovation Program of Shanghai Municipal Education Commission (15ZZ031).

语种：英文

外文关键词：Chlorine compounds - Core shell nanoparticles - Metal nanoparticles - Molar ratio - Nanocatalysts - Olefins - Shells (structures) - Synthesis (chemical) - X ray photoelectron spectroscopy

摘要：A new strategy has been proposed for synthesizing Co@CoO core-shell nanoparticles with a core-shell structure, which involves a facile solvent-thermal process in deep eutectic solvents (DESs). In contrast to the irregular sheet-like packing material obtained in water, twinned and 3D-ellipsoid-shaped nanoparticles were achieved in choline chloride (ChCl)/glycerol and ChCl/PEG-300, respectively. It was found that the nanoparticles were featured as metal Co(0) cores homogeneously wrapped by CoO shells after reduction under a H-2 atmosphere. The Co@CoO core-shell nanoparticles showed good activity and stability for the hydroformylation of olefins, and the conversion of 1-octene can reach 99% at 130 degrees C under 4 MPa (CO/H-2 = 1) pressure, and the selectivity to C-9 aldehydes was reached up to 97%. The characterization by XPS, H-2-TPR and HRTEM indicated that metal Co(0) species could be an active site for hydroformylation of olefins. Notably, the leaching of cobalt carbonyl species was highly dependent on the surface molar ratio of Co2+/Co-0 as revealed by XPS spectra, and the surface CoO layer played an important role in suppressing the loss of active Co species in hydroformylation of olefins. Moreover, the core-shell nano-catalysts are easily separated magnetically from the reaction mixture and showed good recyclability in nine consecutive catalytic runs.