文献类型：期刊文献

中文题名：三氯化锑和二氧杂环己烷配合物[SbCl_3·{(CH_2)_4O_2}_(1.5)]的合成与晶体结构(英文)

英文题名：Synthesis and Crystal Structure of t he Complex of Antimony Trichloride and Dioxane

作者：臧祥生[1];陈娅如[1];栾绍嵘[1];钟国清[2];郭应臣[3]

机构：[1]华东理工大学化学系,上海200237;[2]四川畜牧兽医学院,重庆402460;[3]南阳师范学院化学系,南阳473061

年份：2001

卷号：17

期号：6

起止页码：901

中文期刊名：无机化学学报

外文期刊名：Chinese Journal of Inorganic Chemistry

收录：CSTPCD;;Scopus;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

基金：国家自然科学基金资助项目(No.29771011)

语种：中文

中文关键词：三氯化锑;二氧杂环己烷;配合物;合成;晶体结构;[SbCl3·{(CH2)4O2}1.5]

外文关键词：dioxane complex of antimony trichloride synthesis; crystal structure

摘要：New solid complex of the antimony trichloride and dioxane was obtained th rough a reaction of the dioxane and the absolute methanol solution of the antimony trichloride.The formula of the complex is[SbCl3·｛(CH2)4O2｝1.5].The crystal structure of the comple x belongs to cubic system,space group I-43d,a=17.1417(5)?,Z =16.The trivalent antimony ion n ot only bonds directly to three chlorine anions,but also is co ordinated by three oxygen atoms of th e dioxane molecules.Two oxygen atoms in a dioxane molecule wi ll coordinate to different antimony ions,respectively.
New solid complex of the antimony trichloride and dioxane was obtained through a reaction of the dioxane and the absolute methanol solution of the antimony trichloride. The formula of the complex is [SbCl3 . {(CH2)(4)O-2}(1.5)]. The crystal structure of the complex belongs to cubic system, space group I-43d, a = 17.1417 (5) Angstrom, Z = 16. The trivalent antimony ion not only bonds directly to three chlorine anions, but also is coordinated by three oxygen atoms of the dioxane molecules. Two oxygen atoms in a dioxane molecule will coordinate to different antimony ions, respectively.