文献类型：期刊文献

英文题名：High atomic utilization conversion of ethers into furancarbaldehydes via an ether oxidation iminium-ion activation cascade strategy

作者：Li, Zheyao;Ma, Chunmei;Zhao, Lin;Lin, Zhongren;Hu, Yang;Zhao, Jianhong[1];Yu, Xinhong[1]

机构：[1]East China Univ Sci & Technol, Engn Res Ctr Pharmaceut Proc Chem, Shanghai Key Lab New Drug Design, Minist Educ,Sch Pharm, 130 Meilong Rd, Shanghai 200237, Peoples R China; East China Univ Sci & Technol, State Key Lab Bioengn Reactors, 130 Meilong Rd, Shanghai 200237, Peoples R China

年份：2023

卷号：21

期号：40

起止页码：8094

外文期刊名：ORGANIC & BIOMOLECULAR CHEMISTRY

收录：;EI(收录号：20234314940676);WOS:【SCI-EXPANDED(收录号:WOS:001076959500001)，CCR-EXPANDED(收录号:WOS:001076959500001)】；

基金：We thank the National Natural Science Foundation of China (no. 21476078) and the Science and Technology Commission of Shanghai Municipality (no. 12431900902) for financial support.

语种：英文

外文关键词：Chemical activation - Ions - Oxidation - Synthesis (chemical)

摘要：A novel organocatalytic one-pot cascade ether oxidation iminium-ion activation strategy for the synthesis of naphtho[2,1-b]furan-1-carbaldehyde and benzofuran-3-carbaldehyde from high atomic utilization transformation of aryl allyl ethers has been developed. Its synthetic application will provide a new ether oxidation iminium-ion activation cascade tool for the efficient synthesis of complex molecules.