文献类型：期刊文献

中文题名：镍取代云母蒙脱石的结构表征

英文题名：Structural Charactertization of Nickel-Substituted Mica Montmorillonite

作者：宋学敏[1];陆善祥[1];徐止戈[1];李承烈[1];刘馥英[1]

机构：[1]Laval大学,华东理工大学联合化学反应工程研究所,华东理工大学化学系,华东理工大学石油加工研究所

年份：1994

卷号：20

期号：4

起止页码：528

中文期刊名：华东理工大学学报（自然科学版）

外文期刊名：Journal of East China University of Science and Technology

收录：CSTPCD;;国家哲学社会科学学术期刊数据库;Scopus;CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：镍;催化剂;蒙脱石;云母蒙脱石;XRD

外文关键词：clay mineral;Nickel;X-ray diffraction analysis;IR spectra;catalyst;mont-morillonite

摘要：对不同镍含量的镍取代云母蒙脱石（ＮｉＳＭＭ）样品，通过ＸＲＤ分析，阳离子交换容量和比表面积测定，证明随着镍含量的）增加，镍越来越多地进入到单元层结构中。ＮｉＳＭＭ具有与天然蒙脱石相同的层状结构，其层间填充着可被交换的阳离子。这些阳离子大多数是ＸＲＤ的ｄ＿（０６０）值和红外光谱的骨架振动吸收带进一步表明，镍是进入到单元层中八面体片的六配位中心离子的位置上。ＮｉＳＭＭ的结构稳定性高于天然蒙脱石。
The structure of NiSM M(Nickel-Substituted Mica Montmorillonite) samplesprepared under different conditions were characterized by means of XRD analysis,CEC andsurface area measurements,and IR analysis. It was shown that mote nickel enters the layerstructure of NiSM M when more nickel is added to starting matcrials for the synthesis. NIS-MM has the same layer structure as that in natural smectite.There are exchangable cationsbetween the layers, most of which are The d_(060) value of XRD pattern and the skeletalvibration of IR spectra reveal that nickel ions are located at the centers of octahedra inthe unit layer of NiSMM.