文献类型：期刊文献

英文题名：Straightforward selective synthesis of linear 1-O-alkyl glycerol and di-glycerol monoethers

作者：Shi, Yan[1,2,3];Dayoub, Wissam[1];Favre-Reguillon, Alain[1,4];Chen, Guo-Rong[2,3];Lemaire, Marc[1]

机构：[1]Univ Lyon 1, Lab Catalyse & Synth Organ, ICBMS, CNRS,UMR5246, F-69622 Villeurbanne, France;[2]E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China;[3]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[4]CNAM, Lab Transformat Chim & Pharmaceut, UMR7084, F-75003 Paris, France

年份：2009

卷号：50

期号：49

起止页码：6891

外文期刊名：TETRAHEDRON LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000271603000042)，CCR-EXPANDED(收录号:WOS:000271603000042)】；

基金：Financial support provided in the frame of the MIRA collaborative program between Shanghai City (PR China) and Region Rhone-Alpes is greatly appreciated. China Scholarship Council is also gratefully acknowledged for Ph.D. grants to S.Y.

语种：英文

外文关键词：Reductive alkylation; Glycerol; Di-glycerol; 1-O-Alkyl mono- and di-glycerol monoethers

摘要：1-O-Alkyl glycerol and di-glycerol monoethers are, respectively, obtained in high yields and selectivity by catalytic reductive etherification of mono- and di-glycerol with linear aldehydes in the presence of 0.5 mol % of Pd/C under 10 bars of hydrogen using a Bronsted acid as co-catalyst. (C) 2009 Elsevier Ltd. All rights reserved.