文献类型：期刊文献

中文题名：Zeolite-confined Fe-site Catalysts for the Hydrogenation of CO_(2) to Produce High-value Chemicals

英文题名：Zeolite-confined Fe-site Catalysts for the Hydrogenation of CO2 to Produce High-value Chemicals

作者：Han, Xiaoyang[1,2];Xia, Huicong[1,2];Tu, Weifeng[3];Wei, Yifan[1,2];Xue, Dongping[1,2];Li, Minhan[1,2];Yan, Wenfu[4];Zhang, Jia-Nan[1,2];Han, Yi-Fan[3,5]

机构：[1]Zhengzhou Univ, Coll Mat Sci & Engn, Zhengzhou 450001, Peoples R China;[2]Zhengzhou Univ, State Key Lab Coking Coal Resources Green Exploita, Zhengzhou 450001, Peoples R China;[3]Zhengzhou Univ, Sch Chem Engn, Engn Res Ctr Adv Funct Mat Mfg, Minist Educ, Zhengzhou 450001, Peoples R China;[4]Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China;[5]East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2024

卷号：40

期号：1

起止页码：78

中文期刊名：Chemical Research in Chinese Universities

外文期刊名：CHEMICAL RESEARCH IN CHINESE UNIVERSITIES

收录：CSTPCD;;Scopus;WOS:【SCI-EXPANDED(收录号:WOS:001133003700002)】；CSCD:【CSCD2023_2024】；PubMed;

基金：This work was supported by the National Natural Science Foundation of China (Nos. U22A20107, U1967215, 22078307, 22208314, 22278379, 22238003, and 22002008), the Science and Technology R&D Program Joint Fund Project of Henan Provincial, China (No. 222301420001), the Distinguished Young Scholars Innovation Team of Zhengzhou University, China (No. 32320275), the Postgraduate Education Reform Project of Henan Province, China (No. 2021SJGLX093Y), the National Funded Postdoctoral Researcher Program, China (No. GZC20232382) and the Key Research Projects of University in Henan Province, China (No. 24A150041).

语种：英文

中文关键词：Zeolite-confined Fe-site catalyst;CO_(2) hydrogenation;Modification strategy;High-value chemical

外文关键词：Zeolite-confined Fe-site catalyst; CO2 hydrogenation; Modification strategy; High-value chemical

摘要：Zeolite-confined Fe-site catalysts(ZFCs)have emerged as superior materials for sustainably producing high-value chemicals through CO_(2) hydrogenation,owing to their adaptable framework,customizable composition,and thermal robustness.They excel in activating,adsorbing,and converting CO_(2) with remarkable efficiency and consistency in performance.This has sparked a surge in research interest in recent years.The review delves into the latest advancements in CO_(2) catalytic hydrogenation to olefins,alcohols,aromatics,and other liquid hydrocarbons,examining the synthesis,modification tactics,and the correlation between structure and performance across various ZFCs.Additionally,it underscores the pivotal factors affecting performance and sheds light on the mechanisms behind selectivity control in the CO_(2) hydrogenation process facilitated by ZFCs.To conclude,it presents pressing challenges and strategic recommendations to inspire the development of high-performance,durable ZFCs for CO_(2) hydrogenation applications.
Zeolite-confined Fe-site catalysts (ZFCs) have emerged as superior materials for sustainably producing high-value chemicals through CO2 hydrogenation, owing to their adaptable framework, customizable composition, and thermal robustness. They excel in activating, adsorbing, and converting CO2 with remarkable efficiency and consistency in performance. This has sparked a surge in research interest in recent years. The review delves into the latest advancements in CO2 catalytic hydrogenation to olefins, alcohols, aromatics, and other liquid hydrocarbons, examining the synthesis, modification tactics, and the correlation between structure and performance across various ZFCs. Additionally, it underscores the pivotal factors affecting performance and sheds light on the mechanisms behind selectivity control in the CO2 hydrogenation process facilitated by ZFCs. To conclude, it presents pressing challenges and strategic recommendations to inspire the development of high-performance, durable ZFCs for CO2 hydrogenation applications.