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Surface Equation of State for Pure Phospholipid Monolayer at the Air/Water Interface    

Surface Equation of State for Pure Phospholipid Monolayer at the Air/Water Interface

文献类型:期刊文献

中文题名:Surface Equation of State for Pure Phospholipid Monolayer at the Air/Water Interface

英文题名:Surface Equation of State for Pure Phospholipid Monolayer at the Air/Water Interface

作者:曾作祥[1];陈琼[1];薛为岚[1];聂飞[1]

机构:[1]Institute of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

年份:2004

卷号:12

期号:2

起止页码:263

中文期刊名:Chinese Journal of Chemical Engineering

外文期刊名:中国化学工程学报(英文版)

收录:CSTPCD;;Scopus;CSCD:【CSCD2011_2012】;

基金:Supported by the National Natural Science Foundation of China (No. 20076012).

语种:中文

中文关键词:π-A isotherms; 1;2-dimyristoyphosphatildylcholine; 1;2-dipalmitoylphosphatidylcholine; 1;2-dipal-mitoylphosphatidylglycerol; state equation

外文关键词:单层磷脂;表面平衡现象;空气;水;接触面

摘要:A surface equation of state, applicable to liquid-expanded (LE) monolayers, was derived by analyzing the Helmholtz free energy of the LE monolayers. Based on this equation, a general equation was obtained to describe all states of single-component phospholipid monolayers during comprassion. To verify the applicability of the equation, π-A isotherms of 1,2-dipalmitoylphosphatidylcholine (DPPC), 1,2-dipalmitoylphosphatidylglycerol (DPPG), and 1,2-dimyristoyphosphatildylcholine (DMPC) were measured. The comparison between model and experimental values indicates that the equation can describe the behavior of pure phospholipid monolayers.
A surface equation of state, applicable to liquid-expanded (LE) monolayers, was derived by analyzing the Helmholtz free energy of the LE monolayers. Based on this equation, a general equation was obtained to describe all States of single-component phospholipid monolayers during comprassion. To verify the applicability of the equation, π-A isotherms of 1,2-dipalmitoylphosphatidylcholine (DPPC), 1,2-dipalmitoylphosphatidylglycerol (DPPG), and 1,2-dimyristoyphosphatildylcholine (DMPC) were measured. The comparison between model and experimental values indicates that the equation can describe the behavior of pure phospholipid monolayers.

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