文献类型：期刊文献

中文题名：原子转移自由基聚合及可控自由基聚合

英文题名：Atom Transfer Radical Polymerization and Controlled Radical Polymerization

作者：张兆斌[1];应圣康[1]

机构：[1]华东理工大学活性聚合研究室

年份：1999

期号：3

起止页码：138

中文期刊名：高分子通报

外文期刊名：Polymer Bulletin

收录：CSTPCD;;CSCD:【CSCD2011_2012】；

基金：国家自然科学基金;国家自然科学基金

语种：中文

中文关键词：可控自由基聚合;原子转移;自由基聚合

外文关键词：Atom transfer radical polymerization,Controlled radical polymerization

摘要：以作者在原子转移自由基聚合领域的研究成果为主导，结合国内外文献。
Several important controlled radical polymerization systems developed recently were reviewed by combination of the published literature and the authors' research results on atom transfer radical polymerization (ATRP). In our laboratory,a wide range of novel block copolymers were synthesized by transformation of various mechanism polymerizations(e.g.anion,cation,telomerization and stepgrowth) to ATRP. A series of graft copolymers with controlled branched chains were prepared using halogenation,chloromethylation and ATRP methods. Wellcontrolled fluorinated random copolymers were obtained. Star(co)polymers were also synthesized via multifunctional initiator and coupling approach. In addition,some new catalyst systemswhich based on rare earth metal or using 1,10phenanthroline and bis(2dimethylamionethyl)ether as ligand,were developed. Poly(methyl methacrylate)with bimodal distribution,polystyrene with high melting point and thermoplastic elastomer (PStbPBAbPSt)were prepared by emulsion living radical polymerization. Good prospects for living radical polymerization were also shown.