文献类型：期刊文献

英文题名：Template-controlled Sonogashira cross-coupling reactions on a Au(111) surface

作者：Zhang, Ran[1];Lyu, Guoqing[1];Li, Deng Yuan[2,3];Liu, Pei Nian[2,3];Lin, Nian[1]

机构：[1]Hong Kong Univ Sci & Technol, Dept Phys, Hong Kong, Hong Kong, Peoples R China;[2]East China Univ Sci & Technol, Inst Fine Chem, Meilong Rd 103, Shanghai, Peoples R China;[3]East China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Meilong Rd 103, Shanghai, Peoples R China

年份：2017

卷号：53

期号：10

起止页码：1731

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000395441400040)】；

基金：This work was supported by the Hong Kong RGC 603213, the National Natural Science Foundation of China (Project No. 21421004, 21561162003, 21190033 and 21372072), the Programme of Introducing Talents of Discipline to Universities (B16017).

语种：英文

摘要：We employed three metal-coordination structures as templates to control the Sonogashira cross-coupling reactions on a Au(111) surface catalyzed by loaded Pd. We used scanning tunnelling microscopy to resolve the products formed at the successive reaction steps and identified three vital characteristics for an efficient template: high accessibility of reaction sites, structural rigidity and thermal stability.