文献类型：期刊文献

英文题名：Difluoroaminosulfonylation of Styrenes with N, N-Difluorobenzenesulfonamide

作者：Zhang, Wenqing[1,2];Yang, Xianjin[1,2,3]

机构：[1]East China Univ Sci & Technol, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Inst Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

年份：2021

卷号：248

外文期刊名：JOURNAL OF FLUORINE CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000675502700008)，CCR-EXPANDED(收录号:WOS:000675502700008)】；

基金：This study was financially supported by the National Natural Science Foundation of China (21372077) and by State Key Laboratory of Efficient Utilization for Low Grade Phosphate Rock and Its Associated Resources (WFKF2017-04).

语种：英文

外文关键词：Styrenes; N-Fluorobenzenesulfonamide; N,N-Difluorobenzenesulfonamide; Difluoroaminosulfonylation; Difunctionalization

摘要：A new type of difluoroaminosulfonylation of styrenes with N,N-difluorobenzenesulfonamide (DFBSA) was developed, using NiCl2/Mn as catalysts and bipyridine as the ligand, to afford a series of 1-difluoroamino-2-phenylsulfonyl products. Preliminary mechanistic studies proved a free radical process for the reaction.