文献类型：期刊文献

中文题名：有机磷类成核剂作用下聚丙烯结晶行为及其力学性能

英文题名：THE EFFECT OF ORGANIC PHOSPHORUS NUCLEATING AGENT ON CRYSTALLIZATION BEHAVIORS AND MECHANIC PROPERTIES OF POLYPROPYLENE

作者：桂权德[1];辛忠[1]

机构：[1]华东理工大学聚合物加工研究室,上海200237

年份：2003

卷号：19

期号：4

起止页码：117

中文期刊名：高分子材料科学与工程

外文期刊名：Polymer Materials Science & Engineering

收录：CSTPCD;;Scopus;北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；

基金：中国石化总公司基础研究基金 ( X5 0 0 0 15 );教育部留学回国人员基金资助项目

语种：中文

中文关键词：有机磷;成核剂;聚丙烯;结晶行为;力学性能;成核密度

外文关键词：polypropylene; nucleating agent; crystallization; nucleation density; mechanic property

摘要：研究了含有不同含量成核剂的聚丙烯的结晶行为对其力学性能的影响。结果表明 ,当成核剂含量从 0增至 0 .8% (质量 )时 ,树脂的拉伸强度和弯曲强度提高了 15 % ,弯曲模量增加了 35 % ,结晶温度提高了 10℃ ,由非线性 Volterra积分方程得到的成核密度提高了 10 6倍 ,而且成核聚丙烯的成核密度与其材料的力学性能之间存在着线性关系 ,即随着成核密度的增大 。
The effect of concentration of nucleating agent on crystallization behaviors and mechanics properties of polypropylene has been investigated in this paper. Results show that with the concentration of nucleating agent increasing from 0 to 0.8%, tensile intension and fiexural strength of nucleated polypropylene resin increases 15%, flexural modulus increases 35% and crystallization peak temperature increases 10 ℃ as well as nucleation density calculated from nonlinear Volterra integral equation increases 10 6 times. Moreover, there exits a linear equation between nucleation density and mechanics properties. The mechanics properties increase linearly with the increase of nucleation density.