文献类型：期刊文献

中文题名：用母函数方法处理苯乙烯本体聚合的分子量及其分布

英文题名：Molecular Weight Distribution Solved by Using Generating Functions

作者：曹贵平[1];朱中南[1];乐慧慧[1];张明华[1];沈景慧[1]

机构：[1]联合化学反应工程研究所华东化工学院分所国家重点联合化学工程实验室

年份：1993

卷号：7

期号：2

起止页码：155

中文期刊名：高校化学工程学报

外文期刊名：Journal of Chemical Engineering of Chinese Universities

收录：CSTPCD;;EI(收录号：1994061275910);Scopus;CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：母函数;苯乙烯;聚合;分子量分布

外文关键词：Styrene, Molecular weight distribution, Generating functions

摘要：本文用母函数方法处理了含乙苯的苯乙烯热引发本体聚合系统,建立了分子量分布模型:其中,
A differential model for molecular weight distribution (MWD) is presented by using generating functions. An experimental study of thermal bulk polymerization of styrene with 5～25% ethylbenzene in temperature range of 100～170℃ and conversion range of 0～95% is carried out. Conversion, molecular weight distributions are measured. The model parameters are regressed from the experimental data, and are corrected with the conversions. The calculation indicates that the model agrees with experimental data.