文献类型：期刊文献

英文题名：Core-shell structured CaO-Ca9Al6O18@Ca5Al6O14/Ni bifunctional material for sorption-enhanced steam methane reforming

作者：Chen, Xiangling[1];Yang, Lei[1];Zhou, Zhiming[1];Cheng, Zhenmin[1]

机构：[1]East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2017

卷号：163

起止页码：114

外文期刊名：CHEMICAL ENGINEERING SCIENCE

收录：;EI(收录号：20170503293389);WOS:【SCI-EXPANDED(收录号:WOS:000397357500011)】；

基金：Financial supports from the National Natural Science Foundation of China (21276076), the Program for New Century Excellent Talents in University (NCET-13-0801), the Fundamental Research Funds for the Central Universities (222201313011) and the "111" project (B08021) are gratefully acknowledged.

语种：英文

外文关键词：Sorption-enhanced steam methane; reforming; Core-shell structure; Bifunctional material; H-2 production; Stability

摘要：Sorption-enhanced steam methane reforming (SESMR) is a promising technology for H-2 production, which can be further enhanced at the particle scale by using core (sorbent)-shell (catalyst) structured bifunctional materials. However, it is challenging but desirable to develop such materials with high activity and stability. In this work, three core-shell structured CaO-Ca9Al6O18@Ca5Al6O14/Ni bifunctional materials with varying CaO content and core/shell mass ratio were prepared by a two-step sol-gel method, and two others (Ni/CaO and CaO@Ca5Al6O14/Ni) served as references. The structural properties and catalytic performance of the materials were investigated. The results showed that all core-shell materials during cyclic SESMR operation had much better performance than Ni/CaO with regards to activity, stability and CaO utilization, and CaO-Ca9Al6O18@Ca5Al6O14/Ni was generally superior to CaO@Ca5Al6O14/Ni except when the former had a much higher CaO content than the latter. The excellent performance of CaO-Ca9Al6O18@Ca5Al6O14/Ni was mainly due to the stabilization effect of Ca9Al6O18 and the support effect of Ca5Al6O14. The best material was a CaO-Ca9Al6O18@Ca5Al6O14/Ni with a CaO content of 13 wt% and a core/shell mass ratio of 0.2, showing high activity and stability over 60 SESMR cycles while maintaining nearly complete utilization of CaO. (C) 2017 Elsevier Ltd. All rights reserved.