文献类型：期刊文献

英文题名：Facile AlCl3-Promoted Catalytic Beckmann Rearrangement of Ketoximes

作者：Liu, Li-Feng[1];Liu, Hua[1];Pi, Hong-Jun[1];Yang, Shuo[1];Yao, Min[1];Du, Wenting[1];Deng, Wei-Ping[1]

机构：[1]E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

年份：2011

卷号：41

期号：4

起止页码：553

外文期刊名：SYNTHETIC COMMUNICATIONS

收录：;EI(收录号：20242716596321);WOS:【SCI-EXPANDED(收录号:WOS:000286902000011)，CCR-EXPANDED(收录号:WOS:000286902000011)】；

基金：This work was supported by the Natural Science Foundation of China (No. NSFC 20602011), New Century Excellent Talents in University, the Ministry of Education, China (No. NCET-07-0283), and the "111" Project (No. B07023).

语种：英文

外文关键词：Aluminum chloride; Beckmann rearrangement; ketoxime

摘要：[image omitted] Aluminum chloride, an inexpensive and commercially available Lewis acid traditionally employed for Beckmann rearrangement with stoichiometric amounts, has been now found to smoothly promote the Beckmann rearrangement of various ketoximes to the corresponding amides (up to 99% of yield) with 10mol% catalyst loading in anhydrous acetonitrile under reflux temperature.